Gas Quotes (11)
Chlorine is a deadly poison gas employed on European battlefields in World War I. Sodium is a corrosive metal which burns upon contact with water. Together they make a placid and unpoisonous material, table salt. Why each of these substances has the properties it does is a subject called chemistry.
Broca's Brain: The Romance of Science (1979), footnote. Except reprinted as 'Can We Know the Universe? Reflections on a Grain of Salt,' in John Carey, Eyewitness to Science (1997), 437.
See also: | Chemistry (87) | Chlorine (6) | Poison (17) | Property (11) | Salt (4) | Sodium (7) | Substance (7) | War (51) | Weapon (24)
Compounds of gaseous substances with each other are always formed in very simple ratios, so that representing one of the terms by unity, the other is 1, 2, or at most 3 ... The apparent contraction of volume suffered by gas on combination is also very simply related to the volume of one of them.
Mémoires de la Société d' Arcueil, 1809, 2, 233-4. Trans. Foundations of the Molecular Theory, Alembic Club Reprint, no. 4 (1950), 24.
For if there is any truth in the dynamical theory of gases the different molecules in a gas at uniform temperature are moving with very different velocities. Put such a gas into a vessel with two compartments [A and B] and make a small hole in the wall about the right size to let one molecule through. Provide a lid or stopper for this hole and appoint a doorkeeper, very intelligent and exceedingly quick, with microscopic eyes but still an essentially finite being.
Whenever he sees a molecule of great velocity coming against the door from A into B he is to let it through, but if the molecule happens to be going slow he is to keep the door shut. He is also to let slow molecules pass from B to A but not fast ones ... In this way the temperature of B may be raised and that of A lowered without any expenditure of work, but only by the intelligent action of a mere guiding agent (like a pointsman on a railway with perfectly acting switches who should send the express along one line and the goods along another).
I do not see why even intelligence might not be dispensed with and the thing be made self-acting.
Moral The 2nd law of Thermodynamics has the same degree of truth as the statement that if you throw a tumblerful of water into the sea you cannot get the same tumblerful of water out again.
Whenever he sees a molecule of great velocity coming against the door from A into B he is to let it through, but if the molecule happens to be going slow he is to keep the door shut. He is also to let slow molecules pass from B to A but not fast ones ... In this way the temperature of B may be raised and that of A lowered without any expenditure of work, but only by the intelligent action of a mere guiding agent (like a pointsman on a railway with perfectly acting switches who should send the express along one line and the goods along another).
I do not see why even intelligence might not be dispensed with and the thing be made self-acting.
Moral The 2nd law of Thermodynamics has the same degree of truth as the statement that if you throw a tumblerful of water into the sea you cannot get the same tumblerful of water out again.
Letter to John William Strutt (6 Dec 1870). In P. M. Hannan (ed.), The Scientific Letters and Papers of James Clerk Maxwell (1995), Vol. 2, 582-3.
See also: | Maxwell’s Demon (2) | Molecule (39) | Temperature (5) | Theory (179) | Thermodynamics (15)
For the evolution of science by societies the main requisite is the perfect freedom of communication between each member and anyone of the others who may act as a reagent.
The gaseous condition is exemplified in the soiree, where the members rush about confusedly, and the only communication is during a collision, which in some instances may be prolonged by button-holing.
The opposite condition, the crystalline, is shown in the lecture, where the members sit in rows, while science flows in an uninterrupted stream from a source which we take as the origin. This is radiation of science. Conduction takes place along the series of members seated round a dinner table, and fixed there for several hours, with flowers in the middle to prevent any cross currents.
The condition most favourable to life is an intermediate plastic or colloidal condition, where the order of business is (1) Greetings and confused talk; (2) A short communication from one who has something to say and to show; (3) Remarks on the communication addressed to the Chair, introducing matters irrelevant to the communication but interesting to the members; (4) This lets each member see who is interested in his special hobby, and who is likely to help him; and leads to (5) Confused conversation and examination of objects on the table.
I have not indicated how this programme is to be combined with eating.
The gaseous condition is exemplified in the soiree, where the members rush about confusedly, and the only communication is during a collision, which in some instances may be prolonged by button-holing.
The opposite condition, the crystalline, is shown in the lecture, where the members sit in rows, while science flows in an uninterrupted stream from a source which we take as the origin. This is radiation of science. Conduction takes place along the series of members seated round a dinner table, and fixed there for several hours, with flowers in the middle to prevent any cross currents.
The condition most favourable to life is an intermediate plastic or colloidal condition, where the order of business is (1) Greetings and confused talk; (2) A short communication from one who has something to say and to show; (3) Remarks on the communication addressed to the Chair, introducing matters irrelevant to the communication but interesting to the members; (4) This lets each member see who is interested in his special hobby, and who is likely to help him; and leads to (5) Confused conversation and examination of objects on the table.
I have not indicated how this programme is to be combined with eating.
Letter to William Grylls Adams (3 Dec 1873). In P. M. Harman (ed.), The Scientific Letters and Papers of James Clerk Maxwell (1995), Vol. 2, 1862-1873, 949-50.
See also: | Collision (3) | Colloid (5) | Communication (15) | Conduction (2) | Confusion (3) | Crystal (7) | Eat (7) | Examination (4) | Freedom (13) | Greeting (2) | Irrelevant (2) | Lecture (18) | Programme (2) | Radiation (7) | Remark (2) | Society (24) | Talk (6)
Gases are distinguished from other forms of matter, not only by their power of indefinite expansion so as to fill any vessel, however large, and by the great effect heat has in dilating them, but by the uniformity and simplicity of the laws which regulate these changes.
Theory of Heat (1904), 31.
I call this Spirit, unknown hitherto, by the new name of Gas, which can neither be constrained by Vessels, nor reduced into a visible body, unless the feed being first extinguished. But Bodies do contain this Spirit, and do sometimes wholly depart into such a Spirit, not indeed, because it is actually in those very bodies (for truly it could not be detained, yea the whole composed body should I lie away at once) but it is a Spirit grown together, coagulated after the manner of a body, and is stirred up by an attained ferment, as in Wine, the juyce of unripe Grapes, bread, hydromel or water and Honey.
Oriatrike: Or, Physick Refined, trans. John Chandler (1662), 106.
In your letter you apply the word imponderable to a molecule. Don't do that again. It may also be worth knowing that the aether cannot be molecular. If it were, it would be a gas, and a pint of it would have the same properties as regards heat, etc., as a pint of air, except that it would not be so heavy.
Letter to Lewis Campbell (Sep 1874). In Lewis Campbell and William Garnett, The Life of James Clerk Maxwell (1882), 391.
It must ... be admitted that very simple relations ... exist between the volumes of gaseous substances and the numbers of simple or compound molecules which form them. The first hypothesis to present itself in this connection, and apparently even the only admissible one, is the supposition that the number of integral molecules in any gases is always the same for equal volumes, or always proportional to the volumes. Indeed, if we were to suppose that the number of molecules contained in a given volume were different for different gases, it would scarcely be possible to conceive that the law regulating the distance of molecules could give in all cases relations so simple as those which the facts just detailed compel us to acknowledge between the volume and the number of molecules.
'Essay on a Manner of Determining the Relative Masses of the Elementary Molecules of Bodies, and the Proportions in which they enter into these Compounds', Journal de Physique, 1811, 73, 58-76. In Foundations of the Molecular Theory; Alembic Club Reprints, Number 4 (1923), 28-9.
The results have exhibited one striking feature which has been frequently emphasized, namely that at high pressures all twelve liquids become more nearly like each other. This suggests that it might be useful in developing a theory of liquids to arbitrarily construct a 'perfect liquid' and to discuss its properties. Certainly the conception of a 'perfect gas' has been of great service in the kinetic theory of gases; and the reason is that all actual gases approximate closely to the 'perfect gas.' In the same way, at high pressures all liquids approximate to one and the same thing, which may be called by analogy the 'perfect liquid.' It seems to offer at least a promising line of attack to discuss the properties of this 'perfect liquid,' and then to invent the simplest possible mechanism to explain them.
'Thermodynamic Properties of Twelve Liquids Between 200 and 800 and up to 1200 KGM. Per Sq. Cm.', Memoirs of the American Academy of Arts and Sciences, 1913, 49, 113.
We must make the following remark: a proof, that after a certain time t1, the spheres must necessarily be mixed uniformly, whatever may be the initial distribution of states, cannot be given. This is in fact a consequence of probability theory, for any non-uniform distribution of states, no matter how improbable it may be, is still not absolutely impossible. Indeed it is clear that any individual uniform distribution, which might arise after a certain time from some particular initial state, is just as improbable as an individual non-uniform distribution; just as in the game of Lotto, any individual set of five numbers is as improbable as the set 1, 2, 3, 4, 5. It is only because there are many more uniform distributions than non-uniform ones that the distribution of states will become uniform in the course of time. One therefore cannot prove that, whatever may be the positions and velocities of the spheres at the beginning, the distributions must become uniform after a long time; rather one can only prove that infinitely many more initial states will lead to a uniform one after a definite length of time than to a non-uniform one. Loschmidt's theorem tells us only about initial states which actually lead to a very non-uniform distribution of states after a certain time t1; but it does not prove that there are not infinitely many more initial conditions that will lead to a uniform distribution after the same time. On the contrary, it follows from the theorem itself that, since there are infinitely many more uniform distributions, the number of states which lead to uniform distributions after a certain time t1, is much greater than the number that leads to non-uniform ones, and the latter are the ones that must be chosen, according to Loschmidt, in order to obtain a non-uniform distribution at t1.
'On the Relation of a General Mechanical Theorem to the Second Law of Thermodynamics' (1877), in Stephen G. Brush (ed.), Selected Readings in Physics (1966), Vol. 2, Irreversible Processes, 191-2.
We suppose ... that the constituent molecules of any simple gas whatever (i.e., the molecules which are at such a distance from each other that they cannot exercise their mutual action) are not formed of a solitary elementary molecule, but are made up of a certain number of these molecules united by attraction to form a single one.
'Essay on a Manner of Determining the Relative Masses of the Elementary Molecules of Bodies, and the Proportions in which they enter into these Compounds', Journal de Physique, 1811, 73, 58-76. In Foundations of the Molecular Theory: Alembic Club Reprints, Number 4 (1923), 31.
See also: | Molecule (39)