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Who said: “As far as the laws of mathematics refer to reality, they are not certain; and as far as they are certain, they do not refer to reality.”
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Gas Quotes (30 quotes)

Question: State the relations existing between the pressure, temperature, and density of a given gas. How is it proved that when a gas expands its temperature is diminished?
Answer: Now the answer to the first part of this question is, that the square root of the pressure increases, the square root of the density decreases, and the absolute temperature remains about the same; but as to the last part of the question about a gas expanding when its temperature is diminished, I expect I am intended to say I don't believe a word of it, for a bladder in front of a fire expands, but its temperature is not at all diminished.
Genuine student answer* to an Acoustics, Light and Heat paper (1880), Science and Art Department, South Kensington, London, collected by Prof. Oliver Lodge. Quoted in Henry B. Wheatley, Literary Blunders (1893), 175, Question 1. (*From a collection in which Answers are not given verbatim et literatim, and some instances may combine several students' blunders.)
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Question: State what are the conditions favourable for the formation of dew. Describe an instrument for determining the dew point, and the method of using it.
Answer: This is easily proved from question 1. A body of gas as it ascends expands, cools, and deposits moisture; so if you walk up a hill the body of gas inside you expands, gives its heat to you, and deposits its moisture in the form of dew or common sweat. Hence these are the favourable conditions; and moreover it explains why you get warm by ascending a hill, in opposition to the well-known law of the Conservation of Energy.
Genuine student answer* to an Acoustics, Light and Heat paper (1880), Science and Art Department, South Kensington, London, collected by Prof. Oliver Lodge. Quoted in Henry B. Wheatley, Literary Blunders (1893), 179, Question 12. (*From a collection in which Answers are not given verbatim et literatim, and some instances may combine several students' blunders.)
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[Editorial cartoon showing an executive sitting behind a desk with a Big Oil nameplate]
You want Coal? We own the mines.
You want oil and gas? We own the wells.
You want nuclear energy? We own the uranium.
You want solar power? We own the er..ah..
Solar power isn't feasible.
Newspaper
Mike Peters in Dayton Daily News. Please contact webmaster if you know the date of publication. It was on the cover of the book Solar Gas (1979) by David Hoye.
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After death, life reappears in a different form and with different laws. It is inscribed in the laws of the permanence of life on the surface of the earth and everything that has been a plant and an animal will be destroyed and transformed into a gaseous, volatile and mineral substance.
Quoted in Patrice Debré, Louis Pasteur, trans. Elborg Forster (1994), 110.
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And indeed I am no humming,
Thus to sing of Cl-ke and C-ming,
Who all the universe surpasses
in cutting up and making gases;
With anatomy and chemics,
Metaphysics and polemics,
Analyzing and chirugery,
And scientific surgery ...
H-slow's lectures on the cabbage
Useful are as roots of Babbage;
Fluxions and beet-root botany,
Some would call pure monotony.
Magazine
Punch in Cambridge (28 Jan 1834). In Mark Weatherall, Gentlemen, Scientists, and Medicine at Cambridge 1800-1940 (2000), Vol. 3,77. The professors named were William Clark (anatomy), James Cumming (chemistry) and Johns Stephens Henslow (botany).
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Chlorine is a deadly poison gas employed on European battlefields in World War I. Sodium is a corrosive metal which burns upon contact with water. Together they make a placid and unpoisonous material, table salt. Why each of these substances has the properties it does is a subject called chemistry.
Broca's Brain: The Romance of Science (1979), footnote. Excerpt reprinted as 'Can We Know the Universe? Reflections on a Grain of Salt,' in John Carey, Eyewitness to Science (1997), 437.
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Compounds of gaseous substances with each other are always formed in very simple ratios, so that representing one of the terms by unity, the other is 1, 2, or at most 3 ... The apparent contraction of volume suffered by gas on combination is also very simply related to the volume of one of them.
Mιmoires de la Sociιtι d' Arcueil, 1809, 2, 233-4. Trans. Foundations of the Molecular Theory, Alembic Club Reprint, no. 4 (1950), 24.
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Consider now the Milky Way. Here also we see an innumerable dust, only the grains of this dust are no longer atoms but stars; these grains also move with great velocities, they act at a distance one upon another, but this action is so slight at great distances that their trajectories are rectilineal; nevertheless, from time to time, two of them may come near enough together to be deviated from their course, like a comet that passed too close to Jupiter. In a word, in the eyes of a giant, to whom our Suns were what our atoms are to us, the Milky Way would only look like a bubble of gas.
Science and Method (1908), trans. Francis Maitland (1914), 254-5.
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For if there is any truth in the dynamical theory of gases the different molecules in a gas at uniform temperature are moving with very different velocities. Put such a gas into a vessel with two compartments [A and B] and make a small hole in the wall about the right size to let one molecule through. Provide a lid or stopper for this hole and appoint a doorkeeper, very intelligent and exceedingly quick, with microscopic eyes but still an essentially finite being.
Whenever he sees a molecule of great velocity coming against the door from A into B he is to let it through, but if the molecule happens to be going slow he is to keep the door shut. He is also to let slow molecules pass from B to A but not fast ones ... In this way the temperature of B may be raised and that of A lowered without any expenditure of work, but only by the intelligent action of a mere guiding agent (like a pointsman on a railway with perfectly acting switches who should send the express along one line and the goods along another).
I do not see why even intelligence might not be dispensed with and the thing be made self-acting.
Moral The 2nd law of Thermodynamics has the same degree of truth as the statement that if you throw a tumblerful of water into the sea you cannot get the same tumblerful of water out again.
Letter to John William Strutt (6 Dec 1870). In P. M. Hannan (ed.), The Scientific Letters and Papers of James Clerk Maxwell (1995), Vol. 2, 582-3.
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For me too, the periodic table was a passion. ... As a boy, I stood in front of the display for hours, thinking how wonderful it was that each of those metal foils and jars of gas had its own distinct personality.
[Referring to the periodic table display in the Science Museum, London, with element samples in bottles]
Letter to Oliver Sacks. Quoted in Oliver Sacks, Uncle Tungsten: Memories of a Chemical Boyhood (2001), footnote, 203.
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For the evolution of science by societies the main requisite is the perfect freedom of communication between each member and anyone of the others who may act as a reagent.
The gaseous condition is exemplified in the soiree, where the members rush about confusedly, and the only communication is during a collision, which in some instances may be prolonged by button-holing.
The opposite condition, the crystalline, is shown in the lecture, where the members sit in rows, while science flows in an uninterrupted stream from a source which we take as the origin. This is radiation of science. Conduction takes place along the series of members seated round a dinner table, and fixed there for several hours, with flowers in the middle to prevent any cross currents.
The condition most favourable to life is an intermediate plastic or colloidal condition, where the order of business is (1) Greetings and confused talk; (2) A short communication from one who has something to say and to show; (3) Remarks on the communication addressed to the Chair, introducing matters irrelevant to the communication but interesting to the members; (4) This lets each member see who is interested in his special hobby, and who is likely to help him; and leads to (5) Confused conversation and examination of objects on the table.
I have not indicated how this programme is to be combined with eating.
Letter to William Grylls Adams (3 Dec 1873). In P. M. Harman (ed.), The Scientific Letters and Papers of James Clerk Maxwell (1995), Vol. 2, 1862-1873, 949-50.
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Gases are distinguished from other forms of matter, not only by their power of indefinite expansion so as to fill any vessel, however large, and by the great effect heat has in dilating them, but by the uniformity and simplicity of the laws which regulate these changes.
Theory of Heat (1904), 31.
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I am inclined to think I shall owe ten years of my life to the good effects of the gas, for I inhale about 20 gallons every day in showing patients how to commence. The gas is just like air, only containing a little more oxygen. Oxygen is what gives life and vitality to the blood. We live on oxygen.
Quoted in The Electrical Review (11 Aug 1893), Vol. 33, 143.
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I am now convinced that we have recently become possessed of experimental evidence of the discrete or grained nature of matter, which the atomic hypothesis sought in vain for hundreds and thousands of years. The isolation and counting of gaseous ions, on the one hand, which have crowned with success the long and brilliant researches of J.J. Thomson, and, on the other, agreement of the Brownian movement with the requirements of the kinetic hypothesis, established by many investigators and most conclusively by J. Perrin, justify the most cautious scientist in now speaking of the experimental proof of the atomic nature of matter, The atomic hypothesis is thus raised to the position of a scientifically well-founded theory, and can claim a place in a text-book intended for use as an introduction to the present state of our knowledge of General Chemistry.
In Grundriss der allgemeinen Chemie (4th ed., 1909), Preface, as cited by Erwin N. Hiebert and Hans-Gunther Korber in article on Ostwald in Charles Coulston Gillespie (ed.), Dictionary of Scientific Biography Supplement 1, Vol 15-16, 464.
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I call this Spirit, unknown hitherto, by the new name of Gas, which can neither be constrained by Vessels, nor reduced into a visible body, unless the feed being first extinguished. But Bodies do contain this Spirit, and do sometimes wholly depart into such a Spirit, not indeed, because it is actually in those very bodies (for truly it could not be detained, yea the whole composed body should I lie away at once) but it is a Spirit grown together, coagulated after the manner of a body, and is stirred up by an attained ferment, as in Wine, the juyce of unripe Grapes, bread, hydromel or water and Honey.
Oriatrike: Or, Physick Refined, trans. John Chandler (1662), 106.

If the views we have ventured to advance be correct, we may almost consider {greek words} of the ancients to be realised in hydrogen, an opinion, by the by, not altogether new. If we actually consider the specific gravities of bodies in their gaseous state to represent the number of volumes condensed into one; or in other words, the number of the absolute weight of a single volume of the first matter ({greek words}) which they contain, which is extremely probable, multiples in weight must always indicate multiples in volume, and vice versa; and the specific gravities, or absolute weights of all bodies in a gaseous state, must be multiples of the specific gravity or absolute weight of the first matter, ({Greek words}), because all bodies in the gaseous state which unite with one another unite with reference to their volume.
'Correction of a Mistake in the Essay on the Relation between the Specific Gravities of Bodies in their Gaseous State and the Weights of their Atoms', Annals of Philosophy (1816), 7, 113.
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In your letter you apply the word imponderable to a molecule. Don't do that again. It may also be worth knowing that the aether cannot be molecular. If it were, it would be a gas, and a pint of it would have the same properties as regards heat, etc., as a pint of air, except that it would not be so heavy.
Letter to Lewis Campbell (Sep 1874). In Lewis Campbell and William Garnett, The Life of James Clerk Maxwell (1882), 391.
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It is unlikely that we will ever see a star being born. Stars are like animals in the wild. We may see the very young, but never their actual birth, which is a veiled and secret event. Stars are born inside thick clouds of dust and gas in the spiral arms of the galaxy, so thick that visible light cannot penetrate them.
Perfect Symmetry: The Search for the Beginning of Time (1985), 44.
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It is very different to make a practical system and to introduce it. A few experiments in the laboratory would prove the practicability of system long before it could be brought into general use. You can take a pipe and put a little coal in it, close it up, heat it and light the gas that comes out of the stem, but that is not introducing gas lighting. I'll bet that if it were discovered to-morrow in New York that gas could be made out of coal it would be at least five years before the system would be in general use.
From the New York Herald (30 Jan 1879), as cited in Leslie Tomory, 'Building the First Gas Network, 1812-1820', Technology and Culture (Jan 2011), 52, No. 1, 75-102.
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It must ... be admitted that very simple relations ... exist between the volumes of gaseous substances and the numbers of simple or compound molecules which form them. The first hypothesis to present itself in this connection, and apparently even the only admissible one, is the supposition that the number of integral molecules in any gases is always the same for equal volumes, or always proportional to the volumes. Indeed, if we were to suppose that the number of molecules contained in a given volume were different for different gases, it would scarcely be possible to conceive that the law regulating the distance of molecules could give in all cases relations so simple as those which the facts just detailed compel us to acknowledge between the volume and the number of molecules.
'Essay on a Manner of Determining the Relative Masses of the Elementary Molecules of Bodies, and the Proportions in which they enter into these Compounds', Journal de Physique, 1811, 73, 58-76. In Foundations of the Molecular Theory; Alembic Club Reprints, Number 4 (1923), 28-9.
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Kilometers are shorter than miles. Save gas, take your next trip in kilometers.
Brain Droppings (1998), 72.
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No steam or gas ever drives anything until it is confined. No Niagara is ever turned into light and power until it is tunneled. No life ever grows until it is focused, dedicated, disciplined.
In Living Under Tension Sermons On Christianity Today (1941), 206.
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Recognize that the very molecules that make up your body, the atoms that construct the molecules, are traceable to the crucibles that were once the centers of high mass stars that exploded their chemically rich guts into the galaxy, enriching pristine gas clouds with the chemistry of life. So that we are all connected to each other biologically, to the earth chemically and to the rest of the universe atomically. That's kinda cool! That makes me smile and I actually feel quite large at the end of that. It's not that we are better than the universe, we are part of the universe. We are in the universe and the universe is in us.
From a History Channel TV show, (?) The Universe.
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Sir James Dewar
Is cleverer than you are.
None of you asses
Can condense gases.
Anonymous
In Abraham Pais, Inward Bound: Of Matter and Forces in the Physical World (1986), 137.
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The more important fundamental laws and facts of physical science have all been discovered, and these are now so firmly established that the possibility of their ever being supplanted in consequence of new discoveries is exceedingly remote. Nevertheless, it has been found that there are apparent exceptions to most of these laws, and this is particularly true when the observations are pushed to a limit, i.e., whenever the circumstances of experiment are such that extreme cases can be examined. Such examination almost surely leads, not to the overthrow of the law, but to the discovery of other facts and laws whose action produces the apparent exceptions. As instances of such discoveries, which are in most cases due to the increasing order of accuracy made possible by improvements in measuring instruments, may be mentioned: first, the departure of actual gases from the simple laws of the so-called perfect gas, one of the practical results being the liquefaction of air and all known gases; second, the discovery of the velocity of light by astronomical means, depending on the accuracy of telescopes and of astronomical clocks; third, the determination of distances of stars and the orbits of double stars, which depend on measurements of the order of accuracy of one-tenth of a second-an angle which may be represented as that which a pin's head subtends at a distance of a mile. But perhaps the most striking of such instances are the discovery of a new planet or observations of the small irregularities noticed by Leverrier in the motions of the planet Uranus, and the more recent brilliant discovery by Lord Rayleigh of a new element in the atmosphere through the minute but unexplained anomalies found in weighing a given volume of nitrogen. Many other instances might be cited, but these will suffice to justify the statement that “our future discoveries must be looked for in the sixth place of decimals.”
Light Waves and Their Uses (1903), 23-4.
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The results have exhibited one striking feature which has been frequently emphasized, namely that at high pressures all twelve liquids become more nearly like each other. This suggests that it might be useful in developing a theory of liquids to arbitrarily construct a 'perfect liquid' and to discuss its properties. Certainly the conception of a 'perfect gas' has been of great service in the kinetic theory of gases; and the reason is that all actual gases approximate closely to the 'perfect gas.' In the same way, at high pressures all liquids approximate to one and the same thing, which may be called by analogy the 'perfect liquid.' It seems to offer at least a promising line of attack to discuss the properties of this 'perfect liquid,' and then to invent the simplest possible mechanism to explain them.
'Thermodynamic Properties of Twelve Liquids Between 200 and 800 and up to 1200 KGM. Per Sq. Cm.', Memoirs of the American Academy of Arts and Sciences, 1913, 49, 113.
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The wild gas, the fixed air is plainly broke loose: but we ought to suspend our judgments until the first effervescence is a little subsided, till the liquor is cleared, and until we see something deeper than the agitation of the troubled and frothy surface.
[About the “spirit of liberty;” alluding to Priestley's Observations on Air]
Reflections on the Revolution in France (1790), 8.
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We live at the bottom of a deep gravity well, on the surface of a gas-covered planet going around a nuclear fireball 90 million miles away.
In The Salmon of Doubt: Hitchhiking the Galaxy One Last Time (2002), 132.
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We must make the following remark: a proof, that after a certain time t1, the spheres must necessarily be mixed uniformly, whatever may be the initial distribution of states, cannot be given. This is in fact a consequence of probability theory, for any non-uniform distribution of states, no matter how improbable it may be, is still not absolutely impossible. Indeed it is clear that any individual uniform distribution, which might arise after a certain time from some particular initial state, is just as improbable as an individual non-uniform distribution; just as in the game of Lotto, any individual set of five numbers is as improbable as the set 1, 2, 3, 4, 5. It is only because there are many more uniform distributions than non-uniform ones that the distribution of states will become uniform in the course of time. One therefore cannot prove that, whatever may be the positions and velocities of the spheres at the beginning, the distributions must become uniform after a long time; rather one can only prove that infinitely many more initial states will lead to a uniform one after a definite length of time than to a non-uniform one. Loschmidt's theorem tells us only about initial states which actually lead to a very non-uniform distribution of states after a certain time t1; but it does not prove that there are not infinitely many more initial conditions that will lead to a uniform distribution after the same time. On the contrary, it follows from the theorem itself that, since there are infinitely many more uniform distributions, the number of states which lead to uniform distributions after a certain time t1, is much greater than the number that leads to non-uniform ones, and the latter are the ones that must be chosen, according to Loschmidt, in order to obtain a non-uniform distribution at t1.
'On the Relation of a General Mechanical Theorem to the Second Law of Thermodynamics' (1877), in Stephen G. Brush (ed.), Selected Readings in Physics (1966), Vol. 2, Irreversible Processes, 191-2.
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We suppose ... that the constituent molecules of any simple gas whatever (i.e., the molecules which are at such a distance from each other that they cannot exercise their mutual action) are not formed of a solitary elementary molecule, but are made up of a certain number of these molecules united by attraction to form a single one.
'Essay on a Manner of Determining the Relative Masses of the Elementary Molecules of Bodies, and the Proportions in which they enter into these Compounds', Journal de Physique, 1811, 73, 58-76. In Foundations of the Molecular Theory: Alembic Club Reprints, Number 4 (1923), 31.
Science quotes on:  |  Molecule (80)


Carl Sagan Thumbnail In science it often happens that scientists say, 'You know that's a really good argument; my position is mistaken,' and then they would actually change their minds and you never hear that old view from them again. They really do it. It doesn't happen as often as it should, because scientists are human and change is sometimes painful. But it happens every day. I cannot recall the last time something like that happened in politics or religion. (1987) -- Carl Sagan
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- 90 -
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- 70 -
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