Activation Quotes (4 quotes)
I watched Baeyer activating magnesium with iodine for a difficult Grignard reaction; it was done in a test tube, which he watched carefully as he moved it gently by hand over a flame for three quarters of an hour. The test tube was the apparatus to Baeyer.
I would clarify that by ‘animal’ I understand a being that has feeling and that is capable of exercising life functions through a principle called soul; that the soul uses the body's organs, which are true machines, by virtue of its being the principal cause of the action of each of the machine's parts; and that although the placement that these parts have with respect to one another does scarcely anything else through the soul's mediation than what it does in pure machines, the entire machine nonetheless needs to be activated and guided by the soul in the same way as an organ, which, although capable of rendering different sounds through the placement of the parts of which it is composed, nonetheless never does so except through the guidance of the organist.
It was obvious—to me at any rate—that the answer was to why an enzyme is able to speed up a chemical reaction by as much as 10 million times. It had to do this by lowering the energy of activation—the energy of forming the activated complex. It could do this by forming strong bonds with the activated complex, but only weak bonds with the reactants or products.
Our atom of carbon enters the leaf, colliding with other innumerable (but here useless) molecules of nitrogen and oxygen. It adheres to a large and complicated molecule that activates it, and simultaneously receives the decisive message from the sky, in the flashing form of a packet of solar light; in an instant, like an insect caught by a spider, it is separated from its oxygen, combined with hydrogen and (one thinks) phosphous, and finally inserted in a chain, whether long or short does not matter, but it is the chain of life. All this happens swiftly, in silence, at the temperature and pressure of the atmosphere, and gratis: dear colleagues, when we learn to do likewise we will be sicut Deus [like God], and we will have also solved the problem of hunger in the world.