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Ludwig Edward Boltzmann
(20 Feb 1844 - 5 Sep 1906)
Austrian physicist.
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Science Quotes by Ludwig Edward Boltzmann (5)
A closer look at the course followed by developing theory reveals for a start that it is by no means as continuous as one might expect, but full of breaks and at least apparently not along the shortest logical path. Certain methods often afforded the most handsome results only the other day, and many might well have thought that the development of science to infinity would consist in no more than their constant application. Instead, on the contrary, they suddenly reveal themselves as exhausted and the attempt is made to find other quite disparate methods. In that event there may develop a struggle between the followers of the old methods and those of the newer ones. The former's point of view will be termed by their opponents as out-dated and outworn, while its holders in turn belittle the innovators as corrupters of true classical science.
— Ludwig Edward Boltzmann
'On the Development of the Methods of Theoretical Physics in Recent Times', Populäre Schriften, Essay 14. Address to the Meeting of Natural Scientists at Munich, 22 September 1899. In Brian McGuinness (ed.), Ludwig Boltzmann: Theoretical Physics and Philosophical Problems, Selected Writings (1974), 79.
S = k log Ω
Carved above his name on his tombstone in the Zentralfriedhof in Vienna.
Carved above his name on his tombstone in the Zentralfriedhof in Vienna.
— Ludwig Edward Boltzmann
Image in Stephen Brush, The Kind of Motion we Call Heat: A History of the Kinetic Theory of Gases in the 19th Century (1976), 609.
Since a given system can never of its own accord go over into another equally probable state but into a more probable one, it is likewise impossible to construct a system of bodies that after traversing various states returns periodically to its original state, that is a perpetual motion machine.
— Ludwig Edward Boltzmann
'The Second Law of Thermodynamics', Populäre Schriften, Essay 3. Address to a Formal meeting of the Imperial Academy of Science, 29 May 1886. In Brian McGuinness (ed.), Ludwig Boltzmann: Theoretical Physics and Philosophical Problems, Selected Writings (1974), 30.
The most ordinary things are to philosophy a source of insoluble puzzles. In order to explain our perceptions it constructs the concept of matter and then finds matter quite useless either for itself having or for causing perceptions in a mind. With infinite ingenuity it constructs a concept of space or time and then finds it absolutely impossible that there be objects in this space or that processes occur during this time ... The source of this kind of logic lies in excessive confidence in the so-called laws of thought.
— Ludwig Edward Boltzmann
'On Statistical Mechanics' (1904), in Theoretical Physics and Philosophical Problems (1974), 164-5.
We must make the following remark: a proof, that after a certain time t1, the spheres must necessarily be mixed uniformly, whatever may be the initial distribution of states, cannot be given. This is in fact a consequence of probability theory, for any non-uniform distribution of states, no matter how improbable it may be, is still not absolutely impossible. Indeed it is clear that any individual uniform distribution, which might arise after a certain time from some particular initial state, is just as improbable as an individual non-uniform distribution; just as in the game of Lotto, any individual set of five numbers is as improbable as the set 1, 2, 3, 4, 5. It is only because there are many more uniform distributions than non-uniform ones that the distribution of states will become uniform in the course of time. One therefore cannot prove that, whatever may be the positions and velocities of the spheres at the beginning, the distributions must become uniform after a long time; rather one can only prove that infinitely many more initial states will lead to a uniform one after a definite length of time than to a non-uniform one. Loschmidt's theorem tells us only about initial states which actually lead to a very non-uniform distribution of states after a certain time t1; but it does not prove that there are not infinitely many more initial conditions that will lead to a uniform distribution after the same time. On the contrary, it follows from the theorem itself that, since there are infinitely many more uniform distributions, the number of states which lead to uniform distributions after a certain time t1, is much greater than the number that leads to non-uniform ones, and the latter are the ones that must be chosen, according to Loschmidt, in order to obtain a non-uniform distribution at t1.
— Ludwig Edward Boltzmann
'On the Relation of a General Mechanical Theorem to the Second Law of Thermodynamics' (1877), in Stephen G. Brush (ed.), Selected Readings in Physics (1966), Vol. 2, Irreversible Processes, 191-2.
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